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1 article(s) from Jing, Yanfeng

Recent advances in copper-catalyzed C–H bond amidation

Jie-Ping Wan and
Yanfeng Jing

Beilstein J. Org. Chem. 2015, 11, 2209–2222, doi:10.3762/bjoc.11.240

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Graphical Abstract

Scheme 1: Copper-catalyzed C–H amidation of tertiary amines.

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Scheme 2: Copper-catalyzed C–H amidation and sulfonamidation of tertiary amines.

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Scheme 3: Copper-catalyzed sulfonamidation of allylic C–H bonds.

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Scheme 4: Copper-catalyzed sulfonamidation of benzylic C–H bonds.

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Scheme 5: Copper-catalyzed sulfonamidation of C–H bonds adjacent to oxygen.

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Scheme 6: Copper-catalyzed amidation and sulfonamidation of inactivated alkyl C–H bonds.

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Scheme 7: Copper-catalyzed amidation and sulfonamidation of inactivated alkanes.

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Scheme 8: Copper-catalyzed intramolecular C–H amidation for lactam synthesis.

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Scheme 9: Copper-catalyzed intramolecular C–H amidation for lactam synthesis.

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Scheme 10: Copper-catalyzed amidation/sulfonamidation of aryl C–H bonds.

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Scheme 11: C–H amidation of pyridinylbenzenes and indoles.

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Scheme 12: Mechanism of the Cu-catalyzed C2-amidation of indoles.

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Scheme 13: Copper-catalyzed, 2-phenyl oxazole-assisted C–H amidation of benzamides.

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Scheme 14: DG-assisted amidation/imidation of indole and benzene C–H bonds.

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Scheme 15: Copper-catalyzed C–H amination/amidation of quinoline N-oxides.

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Scheme 16: Copper-catalyzed aldehyde formyl C–H amidation.

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Scheme 17: Copper-catalyzed formamide C–H amidation.

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Scheme 18: Copper-catalyzed sulfonamidation of vinyl C–H bonds.

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Scheme 19: CuCl₂-catalyzed amidation/sulfonamidation of alkynyl C–H bonds.

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Scheme 20: Cu(OH)₂-catalyzed amidation/sulfonamidation of alkynyl C–H bonds.

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Scheme 21: Sulfonamidation-based cascade reaction for the synthesis of tetrahydrotriazines.

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Scheme 22: Copper-catalyzed cascade reaction for the synthesis of quinazolinones.

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Scheme 23: Copper-catalyzed cascade reactions for the synthesis of fused quinazolinones.

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Scheme 24: Copper-catalyzed synthesis of quinazolinones via methyl C–H bond amidation.

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Scheme 25: Dicumyl peroxide-based cascade synthesis of quinazolinones.

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Scheme 26: Copper-catalyzed cascade reactions for the synthesis of indolinones.

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Review

Published 17 Nov 2015

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